Present Status and Future Development of the Forest Chemical Sector
Year:1998 ISSUE:35
COLUMN:SPECIAL REPORT
Click:194 DateTime:Jan.04,2006
Present Status and Future Development
of the Forest Chemical Sector
By Zhao Shoupu
(Senior Engineer of the Forest Chemical Industry Institute
of the Chinese Academy of Forest Sciences)
The forest chemical sector is an industry using forest
products as raw materials to produce various chemical
products by chemical processing methods. After development
for several dozens of years, the forest chemical sector in
China has become an industrial system with more than 600
producers and over 100 product varieties. It holds an
important position in the national economy. Major forest
chemical products include rosin, turpentine, chemical uses
of plant tannin and activated carbon.
1. Rosin and turpentine
China produces 500 000 tons of rosin a year. It is produced
by chemical synthesis mainly using pine gum as raw material.
The domestic output accounts for more than one- third of
the world total. The export amount is over 300 000 tons,
accounting for more than a half of the world rosin trade
amount. Rosin in China holds a swaying role in the world
market and is a major export product in the forest
chemical sector.
The reprocessing of rosin in producers started from the 70
in China. The reprocessing was done by users in the years
before the 70. There is already commercial production of
reprocessed products such as hydrogenated rosin,
disproportionated rosin, maleic rosin, polymerized rosin,
various rosin esters and abietylamine. The output of
turpentine in China is 50 000 - 60 000 tons. Major
reprocessed products include camphor, bornyl alcohol,
terpene resin, terpineol, pine oil,a -pinene, b- pinene,
linalool and isolongifolilene, as well as isolongifolinone
produced from heavy turpentine.
A great deal of research has been done in the recent years
in expanding pine gum recovery capacity and developing new
reprocessed products. There will be a bright prospect for
research and development of rosin polyurethane foamed
plastics, colorless rosin and esters, rosin and modified
rosin emulsions, synthetic peruviol, geraniol, rosin paper
-making sizing material and pinoline resin, as well as
insulation paints, surfactancts and epoxy resins produced
from rosin. Some of the products have already started
production.
China has a history of more than 40 years in rosin
production. To make a stable development of rosin
production, we have to establish raw material bases,
enhance scientific research, cultivate high-yield pine gum
trees and develop specialized and efficient pine gum
recovery. Satisfactory results have already been achieved
in some areas, and further progress will be made in future
. It is expected that by enhancing scientific research and
basic foundation work the rosin sector in China will hold
a leading position in the world in output, technology and
product variety.
2. Chemical uses of plant tannin
The chemical uses of plant tannin in China mainly include
the production of tannin extract and the use of gall nut
tannin. The production of tannin extract mainly uses the
bark of dahuian larch, red bayberry and emblic and valonia
as raw materials. The highest output reached 50 000 tons.
The demand of dark color tannin extract has reduced in the
recent years, and the output today is 10 000 - 15 000 tons
. More than 10 producers make the production of tannic acid
, gallic acid and their derivatives from gall nut. The
output is around 3 000 tons. Besides the traditional
process of acidic hydrolysis, the commercial production of
gallic acid using the process of enzymatic hydrolysis and
alkali hydrolysis has also started. The production of drug
raw materials such as trimethoxyl benzoyl hydrazine,
trimethoxyl benzaldehydride and trimethoprim produced from
tannic acid and gallic acid has made great development and
yielded remarkable economic benefits. The production of
pyrogallic acid has developed fast in China, and the
product is mainly exported to Japan.
In the leather tanning sector, HS retanning agent produced
by complexation of valonia extract with aluminum and
chrome ions has started production and utilization.
Another retanning agent produced by grafting co
-polymerization and modification treatment of dahuian larch
tannin and acrylic monomer has excellent permeating and
filling properties.
Tannin extract made from the bark of dahuian larch and red
bayberry is successfully used to produce tannin adhesives.
They use liquid formaldehyde as curing agent and has a
long-lasting activity and an adjustable viscosity.
Owing to its low price, tannin drilling thinner has been
acclaimed by oil producers. Potassium tannate contained in
the agent has good collapse resistance. The grafting
copolymer of tannin and lignin has the advantage of high
activity in tannin and also the advantage of salt and
temperature resistance in lignin. When used as thinner, it
can perform good comprehensive functions of salt and
temperature resistance, stickiness reduction and water
loss prevention.
Tannin high-temperature blocking agent used to increase the
oil recovery rat