Year:1998 ISSUE:18
COLUMN:OTHER
Click:199 DateTime:Jan.04,2006
Bright Prospects in the Development
of Hydrogen Peroxide Downstream Products
By Guohua
Hydrogen peroxide is an important inorganic chemical product
extensively used in chemical, textile, pharmaceutical, paper- making,
mining, electronic, food and building sectors. The production of
hydrogen peroxide has developed fast in China in the recent years.
There are nearly 70 producers with a capacity of 450 000 t/a and an
output of over 250 000 tons. It is expected that the capacity will
reach 760 000 t/a and the output will reach 560 000 tons in 2000.
Hydrogen peroxide in China is mainly used in bleaching of textiles and
paper pulp, synthesis of chemical products and treatment of wastes.
The consumption in bleaching of textiles and paper pulp accounts for
70% of the total (60% for bleaching of textiles and 10% for bleaching
of paper pulp). The consumption in production of chemical products
only accounts for 23%, and there is much room for development and
application. The development of hydrogen peroxide downstream products
in China will have bright prospects. The article gives a brief
introduction of these downstream products.
(1) sodium percarbonate
China started the production of sodium percarbonate in 1983. Major
producers include Reagent Plant of Jilin Chemical Industrial
Corporation, Tianjin Dongfang Chemical Plant, Guangzhou Zhujiang
Electrochemical Plant, Chongqing Jialing Chemical Plant, Zhejiang
Shangyu Inorganic Salt Chemical Plant and Jiangsu Dantu No. 3 Fine
Chemical Plant. The total capacity is around 9 300 t/a. The product is
mainly used in the detergent sector. The demand is expected to reach
100 000 tons in 2000, and the development will therefore have bright
prospects.
(2) calcium peroxide
Calcium peroxide has extensive uses in agriculture, aquatic cultivation
and environmental protection. Major producers include Wuxi Hongxing
Chemical Plant and Chongqing Jialing Chemical Plant. The product is
mainly used as oxygen-providing agent in coastal high-density aquatic
cultivation and antiseptic and self-cleaning agent in ponds.
(3) methyl ethyl ketone peroxide
Methyl ethyl ketone peroxide is one of organic peroxides with the
greatest consumption in the world. The product is especially suitable
to be used in production lines of polyester button, artificial agate,
glassfiber products and artificial marble. China started small batch
production in 1991, but the output falls far short of the market
demand and it is imperative to make development.
(4) hydrazine hydrate
The total capacity of hydrazine hydrate in China is around 17 000 t/a.
The briskness of the shoe industry in the domestic market and
Southeast Asia has led to an increasing demand of hydrazine hydrate
foaming agents. The demand of sodium azide for automobile safety
bladders is increasing fast. There is also demand in other sectors.
The development of hydrazine hydrate will therefore have bright
prospects.
(5) dimethyl sulfoxide
Major producers of dimethyl sulfoxide in China include Panjin Xinxing
Chemical Plant, Benxi Chemical & Mineral General Plant, Shanxi Yuci
Organic Chemical Plant and Dongya Chemical Plant of Jiaozuo Jiaodong
Mineral Bureau. The total output is 6 000 tons. The product is mainly
used as solvent of fluorocholoraniline for norfloxacin and so on . The
domestic demand of these drugs is increasing fast and both the
capacity and output are expanding. The annual demand of dimethyl
sulfoxide in this sector is expected to be around 6 000 tons in the
next few years. The product is also used as solvent in extraction of
aromatics and synthesis of polyimide, polysulfone resins,
trifluoronitrobenzene and o- and p- nitrofluorobenzene. The annual
demand in this sector will be 2 6000 tons. There is also demand in
other sectors. The annual demand is expected to reach 10 000 tons in
the next few years and 12 000 tons in 2000.
(6) EHP
China has introduced several 300 000 t/a ethylene units in the recent
years. The demand of EHP is therefore increasing and the total demand
can reach over 10 000 tons. There are only 4 producers in China with a
total capacity of less than 1 000 t/a. The great shortage has to be
satisfied by imports.
(7) promoter CPB
It is a super promoter for natural rubber, reclaimed rubber, butadiene
-styrene rubber, butadiene-styrene latex and butadiene- acrylonitrile
rubber. The product is mainly used in production of rubber cloth,
rubber products for medical and surgical use, rubber shoes, water
-proof cloth, self-curing rubber cement and latex products. There is
yet not production in China.
(8) percarbonic amide
The commercial production and application of percarbonic amide in China
is still at the initial stage, but the demand is more than 100 000 tons.
The development and application will therefore have bright prospects.
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